Health and Safety Executive

Safety Report Assessment Guide: Chlorine

Criterion 3.2 "The safety report should demonstrate that the Operator has used information and data that are suitable and sufficient for risk analysis".

A key requirement of the regulations is that information provided about the site and its hazardous substances is suitable and sufficient for a risk assessment. Table 1 provides some examples of where such information may be found. When considering this part of the safety report the assessor should ask if it provides answers to the following questions:-

Q: What is the maximum chlorine inventory and how and under what conditions is it stored?

The site description must describe the location and type of each storage system and provide information on the maximum inventories of chlorine and the conditions (temperature and pressure) under which it is stored.

Q: Does the safety report give a description and explanation of site operations sufficient to enable all potential major accident scenarios to be identified?

The safety report should describe plant and plant operations so that failures and errors having severe consequences can be identified. The detail provided needs to be sufficient to enable Assessors to determine if the accident analysis is thorough and complete. In addition to a full description of the bulk storage vessels, the safety report should describe all other plant with significant chlorine inventory. Plant operations must be described in sufficient detail that failures and errors having severe consequences can be identified.

Q: Are there sufficient maps and plans to allow the location of hazard sources and vulnerable populations/habitats to be identified?

The standard of maps and plans is likely to vary from one report to another, but all the information needed to determine risk should be present. Maps and plans should clearly show the location of large chlorine inventories, populated areas and features of the built and natural environment i.e. the presence of a SSSI or SBI, at risk from the installation. Lists of important features of the local environment are given in the safety report assessment manual.

Q: Can the source terms for all accidents be determined from the information provided?

The information in a safety report must be sufficient to enable the Assessor to deduce the approximate source term for each major accident. In other words, sufficient information should be given to allow the Assessor to determine 'how much, for how long and from where?' Assessors should take the view that any containment system or item of plant can fail and release its contents, therefore the safety report should provide:-

  • The volume of large vessels and other plant containing more than 0.5 tonnes of chlorine (2% threshold), together with their operating pressures and temperatures.
  • The diameter and length of pipe to an isolation valve that can be closed (pipeline failures).
  • A list of equipment such as pumps, regulators and compressors together with the operating pressures and temperatures.
  • A list of ancillary plant and equipment that either contains or is connected to a significant inventory of chlorine ( > 0.5 tonnes).

A safety report that fails to supply all of this information, is unlikely to comply with the assessment criteria.

Q: Are the assumptions used in the accident analysis adequately justified and clearly stated?

The assumptions referred to here do not relate to mathematical modelling of an accident, but are connected with the operation of a site. For example, if the Operator assumes that an alarm will be seen immediately, or that a hardware failure will be detected immediately, the control room must be permanently manned and the instruments that would detect the failure in question should have a status indicator. Even then, the possibility of a delay before remedial or emergency action is taken should be considered. Of particular concern are failures that would allow a large release of gas into the atmosphere to go unnoticed.

Any reliability assumptions about the following should be justified:-

  • ROSOVs to terminate a release.
  • Operators to perform tasks correctly.
  • Instruments to detect a dangerous situation.
  • Shut down systems that respond on demand.

Q: If a QRA approach has been adopted, are accessible sources provided for base failure frequencies/probabilities?

Key documents that the safety report relies on should be available to the Assessor, ideally by being included as an annex to the main report. Fault tree analysis, for example, should not be based on failure probabilities given in a confidential report unless the company is prepared to provide HSE with a copy. The minimum requirements in this respect is references to published work. An Operator's failure to provide any supporting evidence should be considered a failure to comply with the criteria.

Source documents are targets for the follow-up inspection to validate the report, but Assessors should bear in mind their right to request further information from an Operator to help them assess his safety report.

Q: Does the safety report provide, or reference accessible sources for, the predictive models adopted, including the underlying science?

The safety report should provide information on the methods and models used to predict the consequences of major accidents. If a well known computer program such as PHAST has been used, then only details of the input data and the version number are required. If an in-house computer program is used to calculate the consequences of accidents, then the physics on which the predictions are based should be described or reference made to a published article.

Q: Does the safety report describe meteorological conditions, which are appropriate for the site, and in sufficient detail?

A safety report should present wind rose data (wind speed, wind direction and atmospheric stability) for the site in order to establish the frequency and direction of adverse atmospheric conditions. If it presents the consequences of releases under worst conditions identified by wind rose data, an absence of detailed probability data required for a full risk assessment is not a reason for rejecting the report.

Operators should demonstrate awareness of the changes in accident consequences with weather conditions by presenting results for different atmospheric stability and wind speed. They should recognise that the wind direction can vary over 360oC and that D5 and F2 do not necessarily encompass the full range of consequences of an accident. Releases under low wind speed conditions tend to have the worst consequences.

Chlorine releases under ambient conditions are denser than air and

treating them as passive will result in the width of the hazard being underestimated, but the down wind hazard range being over estimated.

Q: Are the features/systems that may limit the consequences of accidents identified?

Operators should not reduce the severity of the consequences of an accident on the grounds of the presence of a safety system. For example, the Operator should not claim that a release will be terminated early by a shutdown system that may fail on demand. Nor should he discount an initiating event on the grounds that a permit-to-work system precludes the necessary conditions.

Ideally, the safety report should quantify the consequences of events with an without safety features operating so that their 'value' can be assessed and balanced against their reliability.

Q: Does the safety report contain all the chemical and physical properties needed to assess the risks from the site?

A safety report should present the entire chemical, physical, toxicological and eco-toxicological information that is needed to calculate risk to people and the environment. In the case of chlorine, this would be primarily chemical reactivity and acute toxicity in addition to more common data such as molecular weight and density.

Table 1 : Sources of data for off-site accident initiators

Initiator Method of model
Aircraft impact AEA methodology
Seismic event British geological survey data
Lightning strike Electricity council data and methodology, BS 6651: 1999
Severe environmental conditions:-

Abnormal rainfall
Abnormal snow fall
Very low temperature
High temperature
Gale force winds

Historical data plus reasoned argument
Flooding Site and met office data plus reasoned argument
Subsidence Historical data plus reasoned argument
Land slip Historical data plus reasoned argument
Fire or explosion at adjoining plant Site environs information plus relevant data where relevant
Missile from off-site Site environs information plus relevant data
Hazardous substance pipeline rupture Site environs information plus relevant data
Collapse of high voltage cable Site environs information plus relevant data
Impact by out of control road or rail vehicle Site environs information plus relevant data
Other  

J.P. Byrne, "The calculation of aircraft risk in the UK", prepared by AEA Technology plc for the Health and Safety Executive 1997. Contact Research Report 150/1997

The method of measuring the frequency of accidents caused by off-site events should be fit for purpose. In other words it should be proportionate to the level of risk. Thus, if a site is located far away from any airport or flight path (military or civil), then it is acceptable for the safety report to refer to the background crash rate for the UK. On the other hand, if the site is located close to a busy airport then a much more detailed assessment of aircraft impact should be carried out.


Directgov - Business Link

23.03.10